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82.
Component based software development (CBSD) is well acknowledged as a methodology which establishes reusability of software and reduce development cost effectively. While developing enterprise application using component based software engineering (CBSE) methods, software component selection plays a very important role in the process of component retrieval, adaptation and assembly. However, most of current researches focus on technical aspects from domain engineering and application engineering to improve reusability and system efficiency rather than application of optimization methods in CBSD management, especially application in component selection. Moreover, few existing researches have concerned about the situation where a software developer or enterprise develops multi-applications at the same time. By introducing the concept of reusability and a new formulation of compatibility matrix, an optimization model is proposed to solve component selection problem considering reusability and compatibility simultaneously. The model can be used to assist software developers in selecting software components when multi-applications are undertaken concurrently. Four experiments are conducted with the purpose to provide some insights in management perspective. 相似文献
83.
Czechoslovak Mathematical Journal - Let $$T(q) = \sum\limits_{k = 1}^\infty {d(k){q^k},\,\,\,\,\left| q \right| < 1,} $$ where d(k) denotes the number of positive divisors of the natural... 相似文献
84.
以山东大学和美国伊利诺伊州立大学香槟分校为基础并结合其他高校的一些做法,对国内外大学的分级教学、教学方式方法、教学层次与效果等进行了对比分析。结果表明,国外大学比较注意教育理念、教学方式和方法,能够有意识地培养学生的兴趣、调动学生学习的积极性,注重教学效果的检测和评价,教学层次和效果明显较高。指出如何改变教育理念和教学方式方法是我国化学类专业实现人才培养目标的关键。 相似文献
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Lu G Kwong FY Ruan JW Li YM Chan AS 《Chemistry (Weinheim an der Bergstrasse, Germany)》2006,12(15):4115-4120
The direct addition of in situ prepared arylzinc to aldehydes with chiral binaphthyl-derived amino alcohols as catalysts can afford optically active diarylmethanols in high yields and with excellent enantioselectivities (up to 99 % ee, ee = enantiomeric excess). By using a single catalyst, both enantiomers of many pharmaceutically interesting diarylmethanols can be obtained by the proper combination of various arylzinc reagents with different aldehydes; this catalytic system also works well for the phenylation of aliphatic aldehydes to give up to 96 % ee. 相似文献
88.
Qiu L Kwong FY Wu J Lam WH Chan S Yu WY Li YM Guo R Zhou Z Chan AS 《Journal of the American Chemical Society》2006,128(17):5955-5965
A series of chiral diphosphine ligands denoted as PQ-Phos was prepared by atropdiastereoselective Ullmann coupling and ring-closure reactions. The Ullmann coupling reaction of the biaryl diphosphine dioxides is featured by highly efficient central-to-axial chirality transfer with diastereomeric excess >99%. This substrate-directed diastereomeric biaryl coupling reaction is unprecedented for the preparation of chiral diphosphine dioxides, and our method precludes the tedious resolution procedures usually required for preparing enantiomerically pure diphosphine ligands. The effect of chiral recognition was also revealed in a relevant asymmetric ring-closure reaction. The chiral tether bridging the two aryl units creates a conformationally rigid scaffold essential for enantiofacial differentiation; fine-tuning of the ligand scaffold (e.g., dihedral angles) can be achieved by varying the chain length of the chiral tether. The enantiomerically pure Ru- and Ir-PQ-Phos complexes have been prepared and applied to the catalytic enantioselective hydrogenations of alpha- and beta-ketoesters (C=O bond reduction), 2-(6'-methoxy-2'-naphthyl)propenoic acid, alkyl-substituted beta-dehydroamino acids (C=C bond reduction), and N-heteroaromatic compounds (C=N bond reduction). An excellent level of enantioselection (up to 99.9% ee) has been attained for the catalytic reactions. In addition, the significant ligand dihedral angle effects on the Ir-catalyzed asymmetric hydrogenation of N-heteroaromatic compounds were also revealed. 相似文献
89.
Lam WW Yiu SM Lee JM Yau SK Kwong HK Lau TC Liu D Lin Z 《Journal of the American Chemical Society》2006,128(9):2851-2858
The oxidation of alkanes and arylalkanes by KMnO(4) in CH(3)CN is greatly accelerated by the presence of just a few equivalents of BF(3), the reaction occurring readily at room temperature. Carbonyl compounds are the predominant products in the oxidation of secondary C-H bonds. Spectrophotometric and kinetics studies show that BF(3) forms an adduct with KMnO(4) in CH(3)CN, [BF(3).MnO(4)](-), which is the active species responsible for the oxidation of C-H bonds. The rate constant for the oxidation of toluene by [BF(3).MnO(4)](-) is over 7 orders of magnitude faster than by MnO(4)(-) alone. The kinetic isotope effects for the oxidation of cyclohexane, toluene, and ethylbenzene at 25.0 degrees C are as follows: k(C6H12)/k(C6D12) = 5.3 +/- 0.6, k(C7H8)/k(C7D8) = 6.8 +/- 0.5, k(C8H10)/k(C8D10) = 7.1 +/- 0.5. The rate-limiting step for all of these reactions is most likely hydrogen-atom transfer from the substrate to an oxo group of the adduct. A good linear correlation between log(rate constant) and C-H bond energies of the hydrocarbons is found. The accelerating effect of BF(3) on the oxidation of methane by MnO(4)(-) has been studied computationally by the Density Functional Theory (DFT) method. A significant decrease in the reaction barrier results from BF(3) coordination to MnO(4)(-). The BF(3) coordination increases the ability of the Mn metal center to achieve a d(1) Mn(VI) electron configuration in the transition state. Calculations also indicate that the species [2BF(3).MnO(4)](-) is more reactive than [BF(3).MnO(4)](-). 相似文献
90.
The full LaCo1−xRhxO3 solid solution was investigated utilizing structural, electrical transport, magnetic, and thermal conductivity characterization. Strong evidence for at least some conversion of Rh3+/Co3+ to Rh4+/Co2+ is found in both structural and electrical transport data. The crystal structure is that of a rhombohedrally distorted perovskite over the range 0.0≤x≤0.1. The common orthorhombic distortion of the perovskite structure is found over the range 0.2≤x≤1.0. A crossover of all three orthorhombic cell edges occurs at x=0.5 giving the appearance of a cubic structure, which actually remains orthorhombic. The octahedra in the orthorhombic structure must be distorted for x values less than 0.5, and the observed distortion suggests orbital ordering for Co2+. Electrical resistivity measurements as a function of temperature show semiconducting-like regions for all compositions. There is a steady increase in electrical resistivity as the Rh content increases. Large positive thermopower values are generally obtained above 475 K. With increasing Rh substitution there is a decrease in thermal conductivity, which slowly rises with increasing temperature due to increased electrical conductivity. The electronic part of the thermal conductivity is suppressed significantly upon Rh substitution. A thermoelectric figure-of-merit (ZT) of about 0.075 has been achieved for LaCo0.5Rh0.5O3 at 775 K, and is expected to reach 0.15 at 1000 K. 相似文献